;5a;7b;8b No.;"δ C, type";"δ H (J in Hz)";"δ C, type";"δ H (J in Hz)";"δ C, type";"δ H (J in Hz)" 1;"14.7, CH3";0.88*;"14.7, CH3";0.87*;"14.5, CH3";"0.87, t (6.9)*" 2;"23.4, CH2";"1.20 ̴ 1.31, m*";"23.4, CH2";"1.20 ̴ 1.31, m*";"23.1, CH2";"1.20 ̴ 1.31, m*" 3;"32.6, CH2";"1.20 ̴ 1.31, m*";"32.6, CH2";"1.20 ̴ 1.31, m*";"32.3, CH2";"1.20 ̴ 1.31, m*" 4;"27.7, CH2";"1.20 ̴ 1.31, m*";"27.7, CH2";"1.20 ̴ 1.31, m*";"27.4, CH2";"1.20 ̴ 1.31, m*" 5;"30.3, CH2";"1.20 ̴ 1.31, m*";"30.3, CH2";"1.20 ̴ 1.31, m*";"30.1, CH2";"1.20 ̴ 1.31, m*" 6;"37.5, CH2";"1.09, m* 1.20-1.31, m*";"37.5, CH2";"1.09, m* 1.20 ̴ 1.31, m*";"37.3, CH2";"1.09, m* 1.20 ̴ 1.31, m*" 7;"33.2, CH";"1.39, m*";"33.2, CH";"1.40, m*";"32.9, CH";"1.38, m*" 7´;"20.0, CH3";0.88*;"20.0, CH3";0.88*;"19.8, CH3";"0.87, d (6.9)*" 8;"36.8, CH2";"1.20 ̴ 1.31* 1.40, m*";"36.9, CH2";"1.20 ̴ 1.31, m* 1.40, m*";"36.6, CH2";"1.20 ̴ 1.31, m* 1.40, m*" 9;"27.2, CH2";"2.19, m*";"27.2, CH2";"2.18, m";"27.0, CH2";"2.21, m*" 10;"144.5, CH";"6.03, br t (7.4)";"144.5, CH";"6.03, br t (7.2)";"144.3, CH";"6.01, t (7.4)" 11;"133.9, C";-;"140.0, C";-;"133.9, C";- 11´;"12.6, CH3";"1.83, s";"12.7, CH3";"1.83, s";"12.5, CH3";"1.85, s" 12;"148.4, CH";"7.54, d (15.7)";"148.3, CH";"7.56, d (15.7)";"148.2, CH";"7.55, d (15.7)" 13;"123.7, CH";"6.40, d (15.7)";"123.8, CH";"6.40, d (15.7)";"123.6, CH";"6.45, d (15.7)" 14;"203.8, C";-;"203.6, C";-;"204.1, C";- 15;"44.5, CH";"2.84, m";"44.6, CH";"2.80 ̴ 2.88, m*";"44.6, CH";"2.88, m" 15´;"17.7, CH3";"1.10, d (6.9)";"17.6, CH3";"1.10, d (6.9)";"17.1, CH3";"1.13, d (6.9)" 16;"28.5, CH2";"1.57, m 1.93 ̴ 2.00, m*";"28.3, CH2";"1.54, m 1.93 ̴ 2.00, m*";"29.1, CH2";"1.66, m 2.04, m*" 17;"30.3, CH2";"1.87, m 1.93 ̴ 2.00, m*";"30.2, CH2";"1.84, m 1.93 ̴ 2.00, m*";"31.3, CH2";"1.97, m 2.04, m*" 18;"77.3, CH";"5.44, m";"77.2, CH";"5.48, m";"77.6, CH";"5.45, m" 19;"44.6, CH";"3.03, quin (7.0)";"44.5, CH";"3.05, quin (7,0)";"45.6, CH";"2.95, m" 19´;"15.8, CH3";"1.30, d (7.0)*";"15.9, CH3";"1.33, d (7.3)*";"14.9, CH3";"1.35, d (7.3)" 20;"173.9, C";-;"174.0, C";-;"173.5, C";- 21-NH;-;"10.43, s";-;"10.55, s";-;"8.15, br s" 22;"139.6, C";-;"139.8, C";-;"50.9, CH";"4.89, m" 22´;"114.6, CH2";"5.60, s 6.24, s";"114.3, CH2";"5.59, s 6.22, s";"17.3, CH3";"1.65, d (7.1)" 23;"165.2, C";-;"165.3, C";;"173.9, C";- 24-NH;-;"7.81, br s";-;"7.88, br t (6.1)";-;"7.96, br s" 25;"43.0, CH2";"3.81, dt (13.5, 6.9) 3.92, dt (13.3, 4.9)";"43.0, CH2";"3.78, dt (13.5, 6.7) 3.94, m";"42.1, CH2";"3.49, dt (13.6, 3.8) 4.04, dt (13.5, 7.9)" 26;"42.7, CH";"2.87, m";"42.7, CH";"2.92, m";"42.8, CH";"2.85, m" 26´;"15.5, CH3";"1.30, d (7.0)*";"15.8, CH3";"1.33, d (7.3)*";"14.9, CH3";"1.22, d (7.3)" 27;"175.0, C";-;"175.1, C";-;"175.4, C";- 28-NH;-;"9.06, br d (7.5)";-;"9.11, br d (7.7)";-;"8.90, br d (7.7)" 29;"53.6, CH";"5.13, dd (14.3, 7.6)";"53.4, CH";"5.18, m*";"53.6, CH";"5.06, dd (12.9, 6.2)" 30;"172.3, C";-;"172.4, C";-;"172.5, C";- 31;"27.6, CH2";"2.63, dt (13.7, 7.0) 2.69 ̴ 2.77, m*";"27.5, CH2";"2.62, dt (13.8, 6.9) 2.71, tt (13.8, 6.9)";"27.3, CH2";"2.51, m 2.68 ̴ 2.74, m*" 32;"32.8, CH2";"2.69 ̴ 2.77, m*";"32.1, CH2";"2.80 ̴ 2.88, m*";"32.7, CH2";"2.68 ̴ 2.74, m*" 33;"175.7, C";-;"176.1, C";-;"176.7, C";- 34-NH2;-;"8.34, s";-;-;-;"8.32, br s"